Fertilizer Defoamer Solutions for Benfield Systems: Foam Control, Market Trends, and Global Applications
In modern fertilizer production, ammonia synthesis relies heavily on efficient CO₂ removal. The Benfield system—one of the most widely used CO₂ absorption technologies—is vital to ammonia, methanol, and urea manufacturing. However, foaming caused by contamination, degradation byproducts, and gas impurities poses a serious operational threat. As feedstock complexity increases and equipment ages, using high-performance fertilizer defoamers has become essential to optimize plant reliability, energy efficiency, and product quality.
Why Fertilizer Defoamer Performance Matters in Benfield CO₂ Absorption Systems?

Understanding Foam Formation and Fertilizer Defoamer Needs in the Benfield Process
The Benfield process absorbs CO₂ using hot, alkaline potassium carbonate solutions. While efficient, the process is prone to foam generation due to:
- Oil-based contaminants in feed gas;
- Catalyst dust and activated carbon fines;
- Additive degradation products;
- Corrosion-related byproducts.
Foaming consequences include:
- Pressure drop across absorber or stripper;
- CO₂ slippage due to entrainment;
- Heat exchanger inefficiencies;
- Risk of plant trips and solvent losses.
Fertilizer defoamers with strong thermal stability, alkali resistance, and fast-acting performance are critical for solving these issues.
Global Fertilizer Defoamer Market Trends for Benfield Systems
Growing Demand in Fertilizer and Ammonia Sectors
Global expansion of nitrogen fertilizer capacity, especially in China, India, and the Middle East, is driving sustained demand for defoamers tailored for Benfield CO₂ absorption systems.
Shift Toward Eco-Friendly, High-Efficiency Fertilizer Defoamers
Modern plant requirements are accelerating the replacement of traditional mineral-oil defoamers with:
- Polyether-based fertilizer defoamers
- Silicone and compound blends
- Features like:
- Thermal stability ≥150°C
- Alkali resistance
- Low VOC emissions
- Compatibility with corrosion inhibitors and DEA solutions
Demand for Long-Term, Low-Dosage Performance
Operators are prioritizing fertilizer defoamers that:
- Perform in highly variable gas feed conditions;
- Reduce dosage frequency and operational costs;
- Maintain stable performance in old or retrofit plants.
Regional Applications of Fertilizer Defoamers in Benfield Systems
China: Coal-Based Ammonia Synthesis Plants
In China, Benfield systems are common in coal-to-ammonia plants. Frequent challenges include volatile raw gas composition and high operating temperatures. Requirements include:
- Long-term thermal stability
- Fast-acting foam knockdown
- Low-dosage effectiveness
- Compatibility with additives and corrosion inhibitors
Case Insight: INVINO-G382fertilizer defoamer successfully replaced UCON 50-HB-5100 in multiple large-scale fertilizer projects.
India: Aging Infrastructure and High Foaming Rates
Old ammonia plants like KRIBHCO and NFL face persistent foam-related disruptions. Ideal fertilizer defoamers must:
- Work in continuous low-dosage settings;
- Avoid precipitation or equipment clogging;
- Remain stable under variable gas loads.
Middle East: HiPure Benfield Systems for LNG Feedstocks
QAFCO and ADNOC utilize Benfield HiPure systems, dealing with complex impurities from LNG. Required fertilizer defoamer characteristics include:
- Rapid foam collapse;
- Ultra-low residue levels;
- Biodegradable formulations;
- Highly concentrated, efficient products.
Competitive Alternatives to Traditional Fertilizer Defoamers in Benfield Systems
The Benfield defoamer market has traditionally been led by multinationals like Dow, BASF, Evonik, and Momentive. However, emerging players from China, India, and the Middle East are gaining market share due to:
- Cost-effective performance
- Faster local support and customization
- Better alignment with sustainability regulations
- DEA and K₂CO₃ compatibility
Example: The INVINO fertilizer defoamer line has successfully replaced imported brands in ammonia and urea plants throughout Asia and the Middle East.
Final Insights and Recommendations for Fertilizer Defoamer Selection
Benfield system foam control is critical to optimizing CO₂ absorption and reducing operating risks. Fertilizer defoamer technology selection should align with your plant’s specific needs:
- Choose a modern fertilizer defoamer type: Polyether or blended defoamers with proven heat and alkali resistance.
- Prioritize process compatibility: Verify DEA and corrosion inhibitor integration.
- Balance sustainability and performance: Go for low-VOC, biodegradable solutions.
- Run performance trials: Validate dosage and efficiency through real plant testing.
Need help selecting the right fertilizer defoamer for your Benfield system?