Fertilizer Defoamer Solutions for Benfield Systems: Foam Control, Market Trends, and Global Applications

In modern fertilizer production, ammonia synthesis relies heavily on efficient CO₂ removal. The Benfield system—one of the most widely used CO₂ absorption technologies—is vital to ammonia, methanol, and urea manufacturing. However, foaming caused by contamination, degradation byproducts, and gas impurities poses a serious operational threat. As feedstock complexity increases and equipment ages, using high-performance fertilizer defoamers has become essential to optimize plant reliability, energy efficiency, and product quality.

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Why Fertilizer Defoamer Performance Matters in Benfield CO₂ Absorption Systems?

fertilizer defoamer

Understanding Foam Formation and Fertilizer Defoamer Needs in the Benfield Process

The Benfield process absorbs CO₂ using hot, alkaline potassium carbonate solutions. While efficient, the process is prone to foam generation due to:

  • Oil-based contaminants in feed gas;
  • Catalyst dust and activated carbon fines;
  • Additive degradation products;
  • Corrosion-related byproducts.

Foaming consequences include:

  • Pressure drop across absorber or stripper;
  • CO₂ slippage due to entrainment;
  • Heat exchanger inefficiencies;
  • Risk of plant trips and solvent losses.

Fertilizer defoamers with strong thermal stability, alkali resistance, and fast-acting performance are critical for solving these issues.

Global Fertilizer Defoamer Market Trends for Benfield Systems

Growing Demand in Fertilizer and Ammonia Sectors

Global expansion of nitrogen fertilizer capacity, especially in China, India, and the Middle East, is driving sustained demand for defoamers tailored for Benfield CO₂ absorption systems.

Shift Toward Eco-Friendly, High-Efficiency Fertilizer Defoamers

Modern plant requirements are accelerating the replacement of traditional mineral-oil defoamers with:

  • Polyether-based fertilizer defoamers
  • Silicone and compound blends
  • Features like:
    • Thermal stability ≥150°C
    • Alkali resistance
    • Low VOC emissions
    • Compatibility with corrosion inhibitors and DEA solutions

Demand for Long-Term, Low-Dosage Performance

Operators are prioritizing fertilizer defoamers that:

  • Perform in highly variable gas feed conditions;
  • Reduce dosage frequency and operational costs;
  • Maintain stable performance in old or retrofit plants.

Regional Applications of Fertilizer Defoamers in Benfield Systems

China: Coal-Based Ammonia Synthesis Plants

In China, Benfield systems are common in coal-to-ammonia plants. Frequent challenges include volatile raw gas composition and high operating temperatures. Requirements include:

  • Long-term thermal stability
  • Fast-acting foam knockdown
  • Low-dosage effectiveness
  • Compatibility with additives and corrosion inhibitors

Case Insight: INVINO-G382fertilizer defoamer successfully replaced UCON 50-HB-5100 in multiple large-scale fertilizer projects.

India: Aging Infrastructure and High Foaming Rates

Old ammonia plants like KRIBHCO and NFL face persistent foam-related disruptions. Ideal fertilizer defoamers must:

  • Work in continuous low-dosage settings;
  • Avoid precipitation or equipment clogging;
  • Remain stable under variable gas loads.

Middle East: HiPure Benfield Systems for LNG Feedstocks

QAFCO and ADNOC utilize Benfield HiPure systems, dealing with complex impurities from LNG. Required fertilizer defoamer characteristics include:

  • Rapid foam collapse;
  • Ultra-low residue levels;
  • Biodegradable formulations;
  • Highly concentrated, efficient products.

Competitive Alternatives to Traditional Fertilizer Defoamers in Benfield Systems

The Benfield defoamer market has traditionally been led by multinationals like Dow, BASF, Evonik, and Momentive. However, emerging players from China, India, and the Middle East are gaining market share due to:

  • Cost-effective performance
  • Faster local support and customization
  • Better alignment with sustainability regulations
  • DEA and K₂CO₃ compatibility

Example: The INVINO fertilizer defoamer line has successfully replaced imported brands in ammonia and urea plants throughout Asia and the Middle East.

Final Insights and Recommendations for Fertilizer Defoamer Selection

Benfield system foam control is critical to optimizing CO₂ absorption and reducing operating risks. Fertilizer defoamer technology selection should align with your plant’s specific needs:

  1. Choose a modern fertilizer defoamer type: Polyether or blended defoamers with proven heat and alkali resistance.
  2. Prioritize process compatibility: Verify DEA and corrosion inhibitor integration.
  3. Balance sustainability and performance: Go for low-VOC, biodegradable solutions.
  4. Run performance trials: Validate dosage and efficiency through real plant testing.

Q&A: Optimizing the Benfield Process

Q: How does the defoamer prevent "Tower Flooding" in the absorber?
Foam accumulation increases the differential pressure ($\Delta P$) in the absorber and stripper columns, leading to "flooding" where gas blocks the liquid flow. Our defoamer rapidly breaks this foam, restoring normal hydrodynamic conditions and preventing costly throughput reductions or shutdowns.
Q: Will the defoamer affect the CO2 absorption efficiency?
On the contrary, it improves it. Foam acts as a barrier to gas-liquid contact. By eliminating the foam layer, the defoamer maximizes the effective surface area for the Potassium Carbonate solution to absorb CO2, thereby maintaining the purity of the hydrogen stream for ammonia synthesis.
Q: Is the product stable in hot Potassium Carbonate solutions?
Yes. The Benfield process operates at high temperatures (approx. 110°C) and high alkalinity. Our **Modified Polyol** series is chemically designed to resist hydrolysis and degradation under these harsh conditions, ensuring long-lasting performance without forming sludge.
Q: Will defoamer carryover affect downstream Urea production?
No. Our defoamers are formulated to be chemically inert and typically used at very low dosages (ppm level). They do not contaminate the CO2 stream sent to the Urea plant, ensuring there is no "oil carryover" that could degrade the final fertilizer quality or crop safety.
Q: Can this also be used for Wet Process Phosphoric Acid (P2O5)?
We have specific grades for Phosphoric Acid. While the Benfield defoamer is optimized for Carbonate systems, our **Phosphoric Acid series** is designed to handle the vigorous foaming from phosphate rock digestion and is stable in strong acidic environments.